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Surflon S-111 : ウィキペディア英語版
Surflon S-111

Surflon S-111 (CAS 72968-3-88) is a commercial product consisting of perfluorinated carboxylic acids (PFCAs) in ammonium salt form. It is commonly used as a polymerization aid in the production of fluoropolymers.
The dominant chemical compound is perfluorononanoic acid (PFNA) at 74% by weight, followed by the 11 carbon perfluoroundecanoic acid (20%), and the 13 carbon perfluorotridecanoic acid (5%).〔 (Supporting Information ) (PDF).〕
Surflon S-111 is synthesized in Japan by oxidizing a mixture of fluorotelomer olefins.〔 Fluorotelomer olefins are synthesized using a telomerization of tetrafluoroethylene taxogens (monomers),〔 followed by an ethylene insertion.〔 The olefin is oxidized, removing one carbon to yield products with an odd number of carbons〔 with even-lengthed fluorocarbon chains plus a carboxylic acid group. As the fluorotelomer olefins are dominated by F(CF2)8CH=CH2,〔 PFNA is the major PFCA product.
Surflon S-111 "is described as Fatty acids, C7-C13, perfluoro, ammonium salts".〔
==See also==

*Fluorosurfactants

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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